Take a look at Albrechts work in @chemsci.bsky.social @royalsocietypublishing.org A series of electron deficient vinylene-linked COFs was prepared and used to host sulfur in cathodes for LiS 🔋 Financed by CRC-1415 @dfg.de pubs.rsc.org/en/content/a...
Missing linker defects form carbonates. After combined 13CO2 adsorption + NMR experiments, new signals appeared in the 13C-MAS NMR 😮. Now, we have a cool new tool to identify and quantify defects in ZIFs and their melt quenched glasses!
Square-triangle tilings could be an infinite topological playground for 2D COFs, but they require precise linker size matching to work. Here we present a system, where we see evidence of linker mixing and heteroepitaxy due to size matching.