Beware of the defects in ZIFs and their glasses ⚠️ With @henkegroup.bsky.social
and the Brunner group @tudresden.bsky.social by NMR we observed that dangling linker imidazoles react with CO2 to form carbamates during adsorption studies - now in Chem. Mater. @acs.org !
pubs.acs.org/doi/10.1021/...
Melt-quenched glasses from zeolitic imidazolate frameworks (ZIFs), a subset of metal–organic frameworks (MOFs) constructed from imidazolate linkers and divalent metal ions, represent a novel class of ...
