Really nice to see the first applications of boratriptycene Boron Lewis acids ( discovered and developed at the University of Namur ) in photo-chemistry. Amazing work by @boron-chemistry.bsky.social @epsrcboron.bsky.social @chemrxiv.org @ezc-group.bsky.social and M. ingleson groups.
G Berionni group
Hey la bonne nouvelle du matin đšâđŹâïž
Olivier RP DAVID
Rethinking #carbolithiation âïž Jacques Maddaluno & co-workers reveal how Liâsubstrate interactions can switch intramolecular alkyne cyclization from syn- to anti-additionđ Predictable #stereocontrol backed by experiment & theory-opening new doors for alkene synthesisđ§Ș
#lithium
đ buff.ly/cZmGp3g
đąHave you checked the program yet?
Outstanding speakers will present their latest research in phosphorus chemistry and related fields. đ§Ș
âïžRegister now and be part of the discussion!
#SWPC26
phoschem-spain.com/Registration...
A very foundational paper by Chris Slootweg @chrisslootweg.bsky.social that helps shed light on FLP chemistry. Weâre glad we were able to make a small contribution here.
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
The latest from the Gilliard and Cummins Labs....on the synthesis and reactivity of dioxaboriranes is now online in @natchem.nature.com (www.nature.com/articles/s41...)! Chonghe synthesized a series of unusual boron-O2 compounds, formed by N2 exchange from diazoboranes! @gilliardgroup.bsky.social
Cyclic peroxides are highly reactive oxygen-containing species that play important roles in chemical synthesis. Now, the reaction between diazoboranes and triplet oxygen affords a family of cyclic dio...
Ok, I can I admit my mistakes. I double-checked the data and corrected two products, here is the updated figure.
Results changed from "disastrous" to "disastrous catastrophe".
#Chemsky #chemchat #SupplementsSaga #TaurateCurse
#supplements and #minerals too
Now slides, one by one:
𧔠1/19
Organic synthesis went sideways; probably the FLP were too frustrated, so they bit off a ring from a couple of BARF-24 anions and glued them together with a hydrogen atom.
This is a second example with such anion, first one is this one dx.doi.org/10.5517/ccdc....
#chemsky #crystallography
Tired of the heat? Chemistry can provide you a solution - just plug in this nanofan to your favourite molecular machine.
as often, from @dr-berionni.bsky.social group.
#chemsky #crystallography
www.ccdc.cam.ac.uk/structures/S...
Looking forward to hosting Antoine Simonneau today from the LCC CNRS in Toulouse! @lcc-smac.bsky.social
Nikolay Tumanov
Nikolay Tumanov
Nikolay Tumanov
How bad is quality of food supplements? If you think that it is bad - you are wrong - it is much worse. Of course, it depend from particular type of supplement, but it could be disastrous, like in the case of "magnesium taurate".
#Chemsky #chemchat #SupplementsSaga #TaurateCurse
𧔠1/x
Nikolay Tumanov
Marcus Drover
chemistry-europe.onlinelibrary.wiley.com
Systematic pnictogen variation (P, As, Sb, Bi) in PnMes3âB(C6F5)3 Frustrated Lewis Pairs (FLPs) reveals how both the energy and intensity of chargeâtransfer excitation can be tuned. Increasing pnicto...
