Professor of chemistry at the University of Namur (Belgium) since 2018.
Organometallic, main-group chemistry, catalysis and organic reactivity. šŖšŗ
G Berionni group
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Really nice to see the first applications of boratriptycene Boron Lewis acids ( discovered and developed at the University of Namur ) in photo-chemistry. Amazing work by @boron-chemistry.bsky.social @epsrcboron.bsky.social @chemrxiv.org @ezc-group.bsky.social and M. ingleson groups.
G Berionni group
Rethinking #carbolithiation āļø Jacques Maddaluno & co-workers reveal how Liāsubstrate interactions can switch intramolecular alkyne cyclization from syn- to anti-additionš Predictable #stereocontrol backed by experiment & theory-opening new doors for alkene synthesisš§Ŗ
#lithium
š buff.ly/cZmGp3g
Hey la bonne nouvelle du matin šØāš¬āļø
š¢Have you checked the program yet?
Outstanding speakers will present their latest research in phosphorus chemistry and related fields. š§Ŗ
āļøRegister now and be part of the discussion!
#SWPC26
phoschem-spain.com/Registration...
Looking forward to hosting Antoine Simonneau today from the LCC CNRS in Toulouse! @lcc-smac.bsky.social
Tired of the heat? Chemistry can provide you a solution - just plug in this nanofan to your favourite molecular machine.
as often, from @dr-berionni.bsky.social group.
#chemsky #crystallography
www.ccdc.cam.ac.uk/structures/S...
Ok, I can I admit my mistakes. I double-checked the data and corrected two products, here is the updated figure.
Results changed from "disastrous" to "disastrous catastrophe".
#Chemsky #chemchat #SupplementsSaga #TaurateCurse
#supplements and #minerals too
Now slides, one by one:
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Organic synthesis went sideways; probably the FLP were too frustrated, so they bit off a ring from a couple of BARF-24 anions and glued them together with a hydrogen atom.
This is a second example with such anion, first one is this one dx.doi.org/10.5517/ccdc....
#chemsky #crystallography
A very foundational paper by Chris Slootweg @chrisslootweg.bsky.social that helps shed light on FLP chemistry. Weāre glad we were able to make a small contribution here.
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
Red-shifting TADF emission with a bora-triptycene Lewis acid ( @chemrxiv.org ) : chemrxiv.org/doi/full/10.... ( @chemguyeli.bsky.social , @ezc-group.bsky.social , @InglesonMike ).
Systematic pnictogen variation (P, As, Sb, Bi) in PnMes3āB(C6F5)3 Frustrated Lewis Pairs (FLPs) reveals how both the energy and intensity of chargeātransfer excitation can be tuned. Increasing pnicto...
The latest from the Gilliard and Cummins Labs....on the synthesis and reactivity of dioxaboriranes is now online in @natchem.nature.com (www.nature.com/articles/s41...)! Chonghe synthesized a series of unusual boron-O2 compounds, formed by N2 exchange from diazoboranes! @gilliardgroup.bsky.social
Carsten von HƤnisch
Nikolay Tumanov
Nikolay Tumanov
Nikolay Tumanov
Cyclic peroxides are highly reactive oxygen-containing species that play important roles in chemical synthesis. Now, the reaction between diazoboranes and triplet oxygen affords a family of cyclic dio...
How bad is quality of food supplements? If you think that it is bad - you are wrong - it is much worse. Of course, it depend from particular type of supplement, but it could be disastrous, like in the case of "magnesium taurate".
#Chemsky #chemchat #SupplementsSaga #TaurateCurse
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