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A story of approximate symmetry and high Z' six years in the making: journals.iucr.org/b/issues/202...
Always great to collaborate with @nclpharmacy.bsky.social. Check out this article In Cell Biochemistry and Biophysics that includes a structure from the Service: link.springer.com/article/10.1...
Apparently I like to pace. A lot.
Pleased to see this study by Erli Lu at @unibirmingham.bsky.social on the reactivity of C-Si bonds in print. Some really cool structures in this one, including two from the Service: onlinelibrary.wiley.com/doi/10.1002/... #chemsky #organometallics
We will be preaching the good word of RODIN at JABC17 on Thursday
15d
1mo
17d
11d
1d
Anionic α-silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a se....
onlinelibrary.wiley.com
The crystal structure of a 2,3,9,9a-tetra­hydro-1H-carbazole in the space group Ia is reported, showing Z′ = 6 and approximate Fdd2 symmetry, and compared to the low Z′ crystal structures of two close...
journals.iucr.org
Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α‐Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes
Structural modification of functionalized carbazoles: from Z′ = 1 to Z′ = 6
The polyfunctional pyrrole 3,5-dichloro-1H-pyrrole-2,4-dicarbaldehyde (2) was reacted with malononitrile and Meldrum’s acid in a regioselective manner to yield derivatives (4, 5, 6, 8, 9, and 10). Com...
link.springer.com
The Synthesis and Biological Activity of Series of New Polyfunctional Pyrroles with the Potential to Modulate Neuronal Viability - Cell Biochemistry and Biophysics
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Happy 100th, deskmate #davidattenborough
Go time!
1mo
Tackling the big issues
Can my next Fisher Scientific order look like this please?
26d
15d
1mo
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
Newcastle Chemical Crystallography Service
1mo
Now online: News & Views on the Article by Roly J. Armstrong, Erli Lu, Koji Kubota, Hajime Ito & co-workers www.nature.com/articles/s44... A mechanochemical route to organosodium by Sobi Asako www.nature.com/articles/s44... ($) #Chemsky
www.nature.com
A simple mechanochemical setup enables the rapid, solvent-free preparation of organosodium compounds directly from sodium lumps without the need for strictly inert conditions, rendering these previous...
A mechanochemical route to organosodium - Nature Synthesis
Nature Synthesis
Aroyo and Brock: A more rational order for the 230 space groups #SpaceGroups #InternationalTablesForCrystallography #IUCr @upvehu...#IUCr https://journals.iucr.org/paper?S1600576726002360
1mo
journals.iucr.org
The current ordering of space groups in Vol. A of International Tables for Crystallography is so full of inconsistencies that its basic patterns are obscured. A revised order based on a small number of principles has been developed. It should be especially useful for teaching.
A more rational order for the 230 space groups
Journal of Applied Crystallography