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The Aldridge group had an amazing time at @eucomc2025.bsky.social. A great selection of talks and some exciting poster discussions! @maxdietz.bsky.social gave a talk, and the rest of the group presented posters.
Really excited to see the first publication of my PhD out now in @angewandtechemie.bsky.social! Great to be a part of this paper with @maxdietz.bsky.social and @josefboronski.bsky.social investigating some exciting tin chemistry.
11mo
Jun 2, 2025
📢Congratulations to the winners of the 2024 Dalton Transactions Outstanding Paper Award🎉 Check out the work from the Holger Braunschweig lab, here: pubs.rsc.org/en/content/a... 📍 ‪@uni-wuerzburg.de 👨‍👩‍👧‍👦 @maxdietz.bsky.social, Merle Arrowsmith, Holger Braunschweig
I am happy to share that our latest paper has been published in @science.org. In this work, we report the synthesis of novel tin carbonyl and carbene complexes. Thanks to all collaborators! www.science.org/doi/10.1126/... @humboldt-foundation.de @oxfordchemistry.bsky.social @ox.ac.uk
We report the first stable hexavalent nickel complex! It's formed by reductive addition of three Be-Be bonds at nickel(0), producing Ni(BeCp)6 pubs.acs.org/doi/10.1021/...
Dec 13, 2024
9mo
10mo
From @maxdietz.bsky.social and Simon Aldridge’s group, an example of a main-group tin-carbonyl complex (@science.org). Above 0 degrees Celsius, this CO complex rearranges to form a tin carbene complex. 🔗 CSD Entry ELAMIR: dx.doi.org/10.5517/ccdc... #FeaturedStructureFriday #CompChemSky
Amelia Swarbrook
Amelia Swarbrook
High-valent nickel species are implicated as intermediates in industrially relevant chemical transformations and in the catalytic cycles of metalloenzymes. Although a small number of tetravalent NiX4 ...
pubs.acs.org
A Crystalline NiX6 Complex
In contrast to transition elements, s- and p-block metal compounds that coordinate carbon monoxide (CO) under near-ambient conditions are elusive. Here, we report an isolable, crystalline main-group m...
www.science.org
A main-group metal carbonyl complex: Structure and isomerization to a carbene-stabilized tin atom
8mo
Dalton Transactions
Maximilian Dietz
Breaking bonds at tin(II)! We've had a look at the spectrum of bond addition reactions, from reductive (Be-Be) to oxidative (Cl-Cl), and everything in between (B-B, B-H, H-H) @angewandtechemie.bsky.social @maxdietz.bsky.social @amelia-swarbrook.bsky.social doi.org/10.1002/anie...
CCDC Cambridge
Josef Boronski
Jun 2, 2025
Video
Here, the addition of H–H, Be–Be, B–B, and B–H bonds to SnII is studied by experimental and theoretical means. We report the first examples of B–B and Be–Be bond additions to a main group metal centr...
doi.org
Breaking Bonds at Tin(II): Reductive or Oxidative Addition?
Josef Boronski