'On Water' hydrogen bonding stabilizes the photo-excited state of quinones: application of Franck-Condon principle in organic synthesis. Congrats to all! #ChemSky #photocatalysis
doi.org/10.1038/s414...
“On-water” photosensitization enables redox neutral acylation and alkylation of quinones
Water-oil interfaces exhibit high cohesive energy density and form a supramolecular hydrogen-bonding network, which supports organic reactions in various ways. Here, the authors introduce the redox-ne...