Our group's very first ACIE paper is out!š„³
Awesome work by Soti and a great cooperation with the Bittl group and @franemmerling.bsky.social.
Dedicated to @christianlimberg.bsky.social and Franc Meyer
@humboldtuni.bsky.social @manchester.ac.uk
onlinelibrary.wiley.com/doi/full/10....
We're delighted to share the success of Marcel Schorpp's (@m-schorpp.bsky.social) first independent article, published in ChemComm!
"A diazadiphospholenium cation featuring a reactive P[double bond, length half m-dash]P bond: synthesis and reversible main-group bond activation"
buff.ly/Lnu0QOR
A Crystalline Phosphorus-Substituted Borinium Ion: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....
Unusual coordination chemistry & reactivity: the methyl #bismuth dication shows a pentagonal pyramidal coordination and can be turned into a Lewis #superacid. Read more about Johannes', @taminazk.bsky.social, and Bene's work in @angewandtechemie.bsky.social: onlinelibrary.wiley.com/doi/10.1002/...!
Happy to see this fun project with @kretschmerlab.bsky.social out.
Two gallium centers in close proximity led to some unexpected outcomes.
Thanks to everyone involved and congrats to the team!
Today two 3rd year students have the pleasure to make some PMe3 in their advanced inorganic lab course! Good job. @likat.bsky.social #31P
We report a high-yielding synthesis of a novel diazadiphospholenium cation featuring a sterically exposed, reactive P [[double bond, length half m-dash]] P bond. It displays aromatic properties and gr...
We present PhD No.4 from the group: Congrats Dr. Ayu! A splendid performance and a PhD period filled with laughter, lab curiosities and brilliant chemistry. Thanks Ayu and all the best for your future!
Also thanks @pchem.bsky.social for being on the committee. #phdone #proudpi #31p
Here's the latest from Goicoechea Group alumnus and master synthetic chemist Chenyang Hu:
onlinelibrary.wiley.com/doi/10.1002/...
Some very elegant double-bond metathesis chemistry allows access to a phosphorus(III) telluride completing our collection of phosphorus-chalcogen double bonds.
The simplistic methylbismuth dication has been captured only by the aid of monodentate tetrahydrofuran (thf) ligands, [BiMe(thf)5]2+. The hexacoordinate species shows a very unusual pentagonal pyrami...
Our latest is out now in @angewandtechemie.bsky.social!
Thermochromism, C-H/O activation & redox chem at a planar Bi triamide. Congrats to PhD Will Howlett on leading this @bsky.app initiated collab with @chrisslootweg.bsky.social + @jasonmasuda.bsky.social
@dalchemistry.bsky.social.
bit.ly/480io3T
Video
Boron Chemistry
Josh Abbenseth
We describe the synthesis and isolation of a phosphinidene telluride. This species acts as a versatile phosphinidene transfer reagent accompanied by the extrusion of elemental tellurium.
TIRE CHANGE: First Mg(I) complex with a Cp* ligand enables facile ligand exchange. Reaction with RONa gives (BDI)Mg-MgOR and Cp*Na. This paves the way for syntheses of many new asymmetric Mg(I) complexes. @angew_chem onlinelibrary.wiley.com/doi/epdf/10....
LabLichtenberg
Hering-Junghans Lab
Hering-Junghans Lab
Hering-Junghans Lab
GoicoecheaGroup
Saurabh Chitnis
Happy to see our joint work with @hering-lab.bsky.social on Gallium/Group 15 Heterocycles that we dedicated to Manfred Scheer on the occasion of his 70th birthday
published. Congrats to the team and many thanks to @dfg.de for funding.
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
Harder Research Group
The ambident reactivity of the bis(gallylene) is demonstrated by the reactions with azobenzene and the triphosphirane (PMes)3, which give rise to a bis(spirocyle) and a 1,2-diphospha-3,4-digalletane,...
