We are Phosphorus Chemsitry enthusiasts.
From Ligand Design with Phosphaalkenes to
Phosphinidene Transfer and Phosphaalumenes.
Located at the LIKAT Rostock.
Hering-Junghans Lab
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Today two 3rd year students have the pleasure to make some PMe3 in their advanced inorganic lab course! Good job. @likat.bsky.social #31P
Happy to see this fun project with @kretschmerlab.bsky.social out.
Two gallium centers in close proximity led to some unexpected outcomes.
Thanks to everyone involved and congrats to the team!
A Crystalline Phosphorus-Substituted Borinium Ion: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....
We present PhD No.4 from the group: Congrats Dr. Ayu! A splendid performance and a PhD period filled with laughter, lab curiosities and brilliant chemistry. Thanks Ayu and all the best for your future!
Also thanks @pchem.bsky.social for being on the committee. #phdone #proudpi #31p
Hering-Junghans Lab
Our latest is out now in @angewandtechemie.bsky.social!
Thermochromism, C-H/O activation & redox chem at a planar Bi triamide. Congrats to PhD Will Howlett on leading this @bsky.app initiated collab with @chrisslootweg.bsky.social + @jasonmasuda.bsky.social
@dalchemistry.bsky.social.
bit.ly/480io3T
Hering-Junghans Lab
Boron Chemistry
Our group's very first ACIE paper is out!š„³
Awesome work by Soti and a great cooperation with the Bittl group and @franemmerling.bsky.social.
Dedicated to @christianlimberg.bsky.social and Franc Meyer
@humboldtuni.bsky.social @manchester.ac.uk
onlinelibrary.wiley.com/doi/full/10....
We're delighted to share the success of Marcel Schorpp's (@m-schorpp.bsky.social) first independent article, published in ChemComm!
"A diazadiphospholenium cation featuring a reactive P[double bond, length half m-dash]P bond: synthesis and reversible main-group bond activation"
buff.ly/Lnu0QOR
Hering-Junghans Lab
Here's the latest from Goicoechea Group alumnus and master synthetic chemist Chenyang Hu:
onlinelibrary.wiley.com/doi/10.1002/...
Some very elegant double-bond metathesis chemistry allows access to a phosphorus(III) telluride completing our collection of phosphorus-chalcogen double bonds.
TIRE CHANGE: First Mg(I) complex with a Cp* ligand enables facile ligand exchange. Reaction with RONa gives (BDI)Mg-MgOR and Cp*Na. This paves the way for syntheses of many new asymmetric Mg(I) complexes. @angew_chem onlinelibrary.wiley.com/doi/epdf/10....
Saurabh Chitnis
Unusual coordination chemistry & reactivity: the methyl #bismuth dication shows a pentagonal pyramidal coordination and can be turned into a Lewis #superacid. Read more about Johannes', @taminazk.bsky.social, and Bene's work in @angewandtechemie.bsky.social: onlinelibrary.wiley.com/doi/10.1002/...!
Josh Abbenseth
ChemComm
GoicoecheaGroup
Harder Research Group
LabLichtenberg
Video
The simplistic methylbismuth dication has been captured only by the aid of monodentate tetrahydrofuran (thf) ligands, [BiMe(thf)5]2+. The hexacoordinate species shows a very unusual pentagonal pyrami...
Happy to see our joint work with @hering-lab.bsky.social on Gallium/Group 15 Heterocycles that we dedicated to Manfred Scheer on the occasion of his 70th birthday
published. Congrats to the team and many thanks to @dfg.de for funding.
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
The ambident reactivity of the bis(gallylene) is demonstrated by the reactions with azobenzene and the triphosphirane (PMes)3, which give rise to a bis(spirocyle) and a 1,2-diphospha-3,4-digalletane,...
We describe the synthesis and isolation of a phosphinidene telluride. This species acts as a versatile phosphinidene transfer reagent accompanied by the extrusion of elemental tellurium.
We report a high-yielding synthesis of a novel diazadiphospholenium cation featuring a sterically exposed, reactive P [[double bond, length half m-dash]] P bond. It displays aromatic properties and gr...
