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Excited about our new @jacs.acspublications.org paper reporting the high-pressure behaviour of MOF-74-type materials 🗜️💎https://doi.org/10.1021/jacs.5c14027. The coolest part: an amine-appended MOF loses long-range order under pressure but fully regains crystallinity when the pressure is released.
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MOF-74 (M2(dobdc); dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate) and its isoreticular derivatives represent a chemically versatile class of metal–organic frameworks (MOFs) with high densities of ope...
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Understanding the High-Pressure Behavior of Honeycomb-Like Metal–Organic Frameworks with Open Metal Sites: Influence of Metal Identity, Linker Extension and Diamine Functionalization
Henke Group