The latest from the group, now out in @angewandtechemie.bsky.social 🥳
We've accessed heavier alkyne-transition metal complexes which show σ-complex character, in contrast to classical π-complexation 😲 All held together by chelation 🧪🫂🧪
Find it here:
onlinelibrary.wiley.com/doi/10.1002/...
onlinelibrary.wiley.com
Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ-comp...
