📣Delighted to share my last collaboration with V. Yu. Kukushkin and K. A. Lotsman, just published in @pubs.acs.org. We report halogen-dependent switching between σ-Hole and π-Hole donor modes in halopolyfluorobiphenyl platforms. @dquimicauib.bsky.social @uib.cat 👏👇
pubs.acs.org/doi/full/10....
This study systematically investigates the halogen-dependent interplay between σ-hole (halogen bonding) and π-hole (perfluoroarene–arene stacking) interactions using a bifunctional perfluoroarene–aren...