Photocatalysis, Supramolecular Catalysis, Total Synthesis, and C-H Activation (student run account)
Bach Lab | TUM
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🎓 Congratulations to our freshly minted PhD, Dr. Johannes Hofer! We’re incredibly proud of you and will truly miss having you around. All the best for your future journey and career! 👏✨ Miau 🐈 #PhDLife #Graduation #photochemistry
Congratulations to our freshly minted PhD Dr. Christoph Buchelt👏 Wishing you all the best for your future 🎓✨ #PhD #graduation
We're very happy to welcome our new Postdoc Dr. Rachel Cantrell! We wish you best of luck for your research 🌟💡👩🔬 #photochemistry #WomeninSTEM
Our new paper on the dearomatization of aromatic carbonyl compounds by photocycloaddition is out now in Organic Letters @pubs.acs.org Congratulations, Luis, for your excellent work 💡🙌💫 #photochemistry pubs.acs.org/doi/10.1021/...
We're very excited to announce our new publication on enantioselective intramolecular C-H Alkylation with Nonsymmetric Chiral Cobalt Porphyrin! Out now in @jacs.acspublications.org 💡🧪https://pubs.acs.org/doi/10.1021/jacs.5c19047
We kicked off the season with an early Christmas party this year and truly enjoyed the evening together with some of our alumni 🌟 Wishing everyone a smooth December and cozy winter days ahead 🎁🎄 #chemistry #alumni #holidays
Excited to share our newest ACS Catalysis paper @pubs.acs.org from Benny, jointly from our lab and @cathleenzeymer.bsky.social on the enantiodivergent evolution of a de novo protein for [2+2] photocycloadditions! 💡🙌
#photochemistry #photoenzyme #biocatalysis 💡🙌
Check out our newest publication on the photochemical deracemization of chromanes! Amazing work @bikig6.bsky.social Out now in @angewandtechemie.bsky.social 💡🌟 #photochemistry #deracemization
doi.org/10.1002/anie...
We're very proud to announce our newest publications on the photochemical cyclization of tertiary buta-2,3-dienamides to β-lactams! A big thanks to the collaborators from the Kerzig Group (@ckerzig.bsky.social) @angewandtechemie.bsky.social #photochemistry 💡🙌🧑🔬
onlinelibrary.wiley.com/doi/10.1002/...
Congratulations to the Bach group (@bach-lab.bsky.social) for this very nice Co-catalyzed asymmetric C-H alkylation, to which we contributed a few DFT calculations: pubs.acs.org/doi/10.1021/...
Energy transfer is the key to the successful photocyclization of the title compounds to 3,4-disubstituted 2-azetidinones. If the substituent at the nitrogen atom is primary (R2 = H), trans products a...
Upon catalysis (1 mol %) by a chiral cobalt porphyrin, quinazolinones with a tethered diazo alkane precursor underwent an enantioselective C–H alkylation at carbon atom C4. Formation of five-, six-, a...
Upon catalysis (1 mol %) by a chiral cobalt porphyrin, quinazolinones with a tethered diazo alkane precursor underwent an enantioselective C–H alkylation at carbon atom C4. Formation of five-, six-, a...
The design of artificial photoenzymes by incorporating synthetic chromophores into proteins represents a promising strategy to achieve non-natural biocatalytic transformations with high levels of ster...
The photocycloaddition of 1,1-dimethylallene to various aromatic carbonyl compounds was found to occur exclusively at the benzene core. While the reaction with methyl 2-methoxybenzoate resulted in a mixture of products resulting from ortho, meta, and para photocycloaddition, acetophenone and its 4-substituted derivatives delivered the respective para photocycloaddition products in 50–58% yields. For 2-methoxyacetophenone, an ortho photocycloaddition initiated a reaction cascade, which led to bicyclic products by the incorporation of a nucleophile in 29–74% yields.
Various substituted chromane-2-carboxamides were successfully deracemized by employing a chiral benzophenone (BP, 10 mol%) as photocatalyst and an achiral thiol as additive (20 mol%). The method was ...
