Check out our latest publication in @angewandtechemie.bsky.social where we show that the infamous V shape in the substituent effects in the thermal isomerization of azobenzenes comes from a single nonadiabatic mechanism 🔥 and not a mix of two.
onlinelibrary.wiley.com/doi/10.1002/...
Unified nonadiabatic switching: thermal Z→E isomerization of para-substituted azobenzenes proceeds through a single nonadiabatic rotational pathway. The iconic bell-shaped Hammett plot is a σp artifa...
