See below for the latest from @alvarogarciaromero.bsky.social. We describe the reversible, redox-neutral carbometallation of a phospha-alkyne to afford a mono-coordinate indium(I) compound. Indium(I) to indium(I), and back again.
onlinelibrary.wiley.com/doi/10.1002/...
The redox neutral carbometallation of a phospha-alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono-coordinate indium(I) compound that can reversibly extrud...