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Do you like phosphorus-containing heterocycles? And NMR spectroscopy? Then you are in for a treat! Check out our most recent work out today in @chemicalscience.rsc.org pubs.rsc.org/en/content/a... Fantastic work by the indefatigable David Meier who persevered when most would have given up.
We describe the synthesis of a phosphanyl-functionalized 1,3,5-triphosphabenzene that exhibits remarkably large indirect spin-spin coupling (432 Hz) between phosphorus-31 nuclei. The magnitude of this...
Exceptionally large “through-space” nuclear spin coupling in a 2,4,6-tri(phosphanyl)-1,3,5-triphosphabenzene
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