In this paper, we revisit one of the earliest reported bis(arene) sandwich complexes, [Fe(C6Me6)2], to finally solve a classic textbook question. As one of the reviewers mentioned, this is one for the organometallics purists!
@chemieverband.bsky.social @kit.edu
pubs.acs.org/doi/full/10....
In this communication, we revisit one of E. O. Fischer’s seminal discoveries to solve a textbook question: is the iron(0) complex [Fe(C6Me6)2] an 18-valence-electron complex with a ‘ring-slip’ (η6,η4)...