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Ambre and Anne-Fred's work exploring Ru-ZnH heterometallics now out in Inorganic Chemistry. Synthesis, mechanism, QTAIM, catalysis and more. In collaboration with the Whittlesey Group @bathchem.bsky.social – see pubs.acs.org/doi/10.1021/...
Mar 4, 2025
ZnH2 as a Precursor to Catalytically Active Ru–ZnH Heterometallic Complexes
Reaction of [Ru(IPr)2(CO)H][BArF4] (1; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; BArF4 = B{3,5(CF3)2C6H3}4) with an excess of ZnH2 in THF gives the structurally characterized neutral Ru...
pubs.acs.org