In our latest pre-print we show it’s possible to access a range of diphosphinoborane ligands with different substitutions on either the boron fragment or phosphine fragment. Congrats to Ryan, @mattdv-t.bsky.social and David.
chemrxiv.org/doi/full/10....
chemrxiv.org
A new synthetic approach to accessing a wide range of diphosphinoborane ligands and their coordination behaviour to low-valent nickel centres is described. The synthetic route negates the use of ArBCl2, which are challenging to access, and utilizes ...