Excited to share my latest project from my time at the Krossing group!š
We show that Nā can bind to a cationic Mn fragment without donor ligands and explore how this affects Nā polarization & binding.
Thanks to all coauthors & collaborators!
š doi.org/10.1021/jacs... @jacs.acspublications.org
Dinitrogen complexes are intermediates in nitrogen fixation. Until now, all isolated molecular dinitrogen complexes have relied on ancillary ligands that are net electron donors, yielding N2 ligands c...