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A nice one! Anyone who worked with group 4 metals knows how hard it is to reach their low ox. state…
1mo
SMAc Team
Check out Emma's new @chemistryworld.com story on seven-coordinate Ti(0) and Zr(0), based on research published in Chemical Science! #ChemSky Read the original article here: doi.org/10.1039/D6SC...
1mo
The stabilization of zero oxidation state group (IV) metal centers in readily accessible compounds on a preparative scale remains a significant challenge. Substituting hydrocarbon ligands in the precu...
doi.org
Homoleptic seven-coordinate Ti(0) and Zr(0) through a new stabilization mode
Chemical Science
Cooperative gallium–gallium interactions underpin the first homoleptic titanium(0) and zirconium(0) complexes’ unprecedented stability. www.chemistryworld.com/news/coopera...
1mo
Strategy could make low-valent metal chemistry a lot more accessible
www.chemistryworld.com
Cooperative gallium bonds unlock zero-valent titanium and zirconium
Chemistry World