Are you interested in radical #chemistry or redox-active ligands?
New work by @brehergroup.bsky.social about the isolation of a stable radical dianion is now in early view @helvchimacta.bsky.social as part of a special issue dedicated to Prof. Dr. Armido Studer.
#chemsky
doi.org/10.1002/hlca...
New paper now out in Early View @angewandtechemie.bsky.social !
We @brehergroup.bsky.social describe radical #photochemistry of main group #organometallics with visible light. With our article we want to make the described concept accessible to a broader #chemistry community.
#Chemsky
Had a wonderful time at #EuCOMC 2025 in Bern! Thank you @evaheviagroup.bsky.social and @albrecht-lab.bsky.social for organizing a really great conference!
Are you interested in Main Group Photochemistry? Check out our recent Review about E-C bond photolysis đ
This article reports on the isolation of a monomeric compound with a dianionic singly reduced bis(pyridylimino) isoindolide (BPI) ligand and elaborated discussions on the structure of reduced BPIs.
The first mono ortho-phenylene bridged Al/P FLP was synthesized and characterized. Its reactivity was probed against several small molecules. Thanks to Melina Dianas đ doi.org/10.1002/ejic...
Jonas Oliver Wenzel
Jonas Oliver Wenzel
Jonas Oliver Wenzel
A detailed study on the reactivity of ambiphilic metallacycles is presented. Thanks to @felixkraemer.bsky.social, @pascalweisenb.bsky.social and @isra-group.bsky.social)! Have a look at the paper đ doi.org/10.1002/ejic...
Jonas Oliver Wenzel
Jonas Oliver Wenzel
Very nice group excursion of the Hinz and Breher lab today! Many thanks to all involved đđđ
#TopViewedArticle đ We are delighted to share that our work, published in EurJIC @wiley.com, has ranked within the top 10% of most-viewed papers published by the journal in 2023 đ doi.org/10.1002/ejic...
Many thanks to @joshabbenseth.bsky.social and Frank Tambornino for highlighting our collaborative study on the organometallic and photochemistry of R2Al(BPI) complexes in âTrendbericht Anorganische Chemie 2025â đđđ
onlinelibrary.wiley.com/doi/10.1002/...
This work reports on the synthesis and characterization of alkali metal complexes of BPI and Me2BPI in reduced oxidation states. CV, EPR and XRD studies revealed detailed information about the unknow...
This minireview discusses the facilitation of EâC bond homolysis of main group compounds with visible light by the coordination of redox non-innocent ligands. Important conceptual coherencies, potent....
Excellent review by @jonasoliverwenzel.bsky.social and Johannes Werner on "Non-Innocent Ligands as Mediators for Visible-Light-Initiated ElementâCarbon Bond Homolysis in Main Group Chemistry" just out in @angewandtechemie.bsky.social đđ
doi.org/10.1002/anie...
Photoinitiated homolysis of element-carbon bonds is an important method for the generation of carbon-centered radicals in catalysis and organometallic or polymer chemistry. In this respect, the use o....
Met some friends at the beautiful #EuCOMC conference in beautiful Bern. @jonasoliverwenzel.bsky.social @pascalweisenb.bsky.social
The unexpected reactivity and stability limits of phosphorus ylide-based aluminum- and gallium-carbon ambiphiles are described. While the previously published t-butyl-substituted compound (2-{AltBu2}...
Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho-phenylene bridge...
