Rethinking Iron Photoredox Catalysis
For Fe(III) complexes, excited-state redox potentials don’t follow the usual rules - standard estimation methods fall short
Joël Wellauer with Paul Francis & colleagues at Deakin University in @jacs.acspublications.org
pubs.acs.org/doi/10.1021/...
pubs.acs.org
The reduction potentials of electronically excited states are crucial input values for photoredox reaction design. Since they are not directly measurable, they are typically estimated from the corresp...