Our research on fluorescent digermanium- and diboron-doped hexacene derivatives is now published in Chemical Science (pubs.rsc.org/en/content/a...)! Heechan and the Romero-Nieto Group unveil Ge-B exchange as a method to obtain boron-doped extended acenes! #maingroup @chemicalscience.rsc.org
Reactions of diazoboranes with oxygen enables the synthesis and isolation of dioxaboriranes ( @rjgilliard.bsky.social , @gilliardgroup.bsky.social ): www.nature.com/articles/s41... ( @natchem.nature.com ).
Check out Nathan's article in @jacs.acspublications.org on luminescent and stimuli-responsive borenium ion materials! #maingroup pubs.acs.org/doi/10.1021/...
The latest from the Gilliard and Cummins Labs....on the synthesis and reactivity of dioxaboriranes is now online in @natchem.nature.com (www.nature.com/articles/s41...)! Chonghe synthesized a series of unusual boron-O2 compounds, formed by N2 exchange from diazoboranes! @gilliardgroup.bsky.social
Our manuscript introducing ion-pair assembly in CDC-borenium ions as a method to unlock red to near-infrared luminescence is now published in Nature Chemistry (www.nature.com/articles/s41...)! Chunlin shows that counteranion modulation directs solid-state emission! #maingroup @natchem.nature.com
Our manuscript on the first isolable paramagnetic boron tetraradical is now online @jacs.acspublications.org (pubs.acs.org/doi/full/10....)! @heechankim.bsky.social designed and synthesized an unusual B-PAH tetraradical with tetraphenylethene-linked boraphenanthrene-type units! #maingroup
Check out this awesome paper by Colleen and coworkers on the redox activity and near-infrared optical properties of doubly boron-doped indenofluorenes (DBIF), now out in @jacs.acspublications.org (pubs.acs.org/doi/10.1021/...)!
Our manuscript on the redox- and protonation-chemistry of diboraheptacenes is published in @jacs.acspublications.org (pubs.acs.org/doi/full/10....)! @JinhyoHwang and @chemheechan report a DBH dianion (w/NIR absorption) that’s the longest fully conjugated boron-doped acene! #maingroup
Our manuscript detailing the impact of carbene ligands on the synthesis, properties, and reactivity of 8 diazoboranes is now published in JACS (pubs.acs.org/doi/10.1021/...)! Take a look at the unusual boraketenes and diazaborles! #maingroup #boron @jacs.acspublications.org
Our manuscript on harnessing substituent and aggregation-induced effects for color-tunable emission in CDP-borafluorenium ions is now published in the Journal of Materials Chemistry C (pubs.rsc.org/en/content/a...)! #maingroup @nathanfrey.bsky.social @gilliardgroup.bsky.social @jmaterchem.rsc.org
Borenium ions are tricoordinate boron cations of the type [LBR2]+, where L is a donor ligand. While the inherently reactive nature of these Lewis acidic species has been harnessed to advance bond acti...
Cyclic peroxides are highly reactive oxygen-containing species that play important roles in chemical synthesis. Now, the reaction between diazoboranes and triplet oxygen affords a family of cyclic dio...
Acenes are attractive molecular platforms with characteristic π-electron delocalization, resulting in exceptionally small HOMO–LUMO gaps, which makes them valuable for use in a variety of organic elec...
