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@hannahredmill.bsky.social 's reaction of a yttrium phosphide complex with carbon dioxide to give a phosphinocarboxylate has just been published as a preprint on @chemrxiv.org: chemrxiv.org/doi/full/10.... Thanks to @jefftyjeffjeff.bsky.social for the help with a gorgeous crystal structure 🤩!
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The insertion of carbon dioxide into rare earth metal-phosphorus bonds is underexplored compared to many other rare earth metal-ligand σ-bonds. Treatment of a C6D6 solution of the dimeric yttrium bis(...
chemrxiv.org
Reaction of a Yttrium Phosphide Complex with Carbon Dioxide Gives a Paddlewheel-Like Phosphinocarboxylate | ChemRxiv
David Mills